Oxidation of π-allylpalladium halides in aqueous solutions

  • A. P. Belov
  • I. I. Moiseev
  • Ya. K. Syrkin
Brief Communications
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Conclusions

  1. 1.

    A study was made of the oxidation-reduction reaction of some π-allylpalladium halides with p-benzoquinone, duroquinone, copper (II), chloride, and bromide, iodine and potassium hexaferricyanide in aqueous solutions that contain halide ion.

     
  2. 2.

    The potential for the oxidation of C3H5PdX 2 , with the formation of allyl halides and tetraacido complexes of palladium (II), decreases in the order X=Cl, Br, I.

     

Keywords

Oxidation Copper Chloride Potassium Aqueous Solution 

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Literature cited

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • A. P. Belov
    • 1
  • I. I. Moiseev
    • 1
  • Ya. K. Syrkin
    • 1
  1. 1.M. V. Lomonosov Moscow Institute of Fine Chemical TechnologyUSSR

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