Skip to main content
SpringerLink
Log in

Complex compounds of platinum(IV) with hydroxylamine

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method was developed for the production of complexes of Pt(IV) with hydroxylamine by bromination of complexes of Pt(II) in CCl4.

  2. 2.

    According to the data of x-electronic spectroscopy, the oxidation state of platinum in complexes of Pt(IV) is equal to +4. The presence of a Pt-Br bond in the complexes was established by the method of IR spectroscopy.

  3. 3.

    Complexes of Pt(IV) with hydroxylamine are stable in solutions of HBr; their electronic absorption spectra were investigated under these conditions. During storage of aqueous solutions of the complexes, they are partially reduced to complexes of Pt(II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. L. A. Chugaev and I. I. Chernyaev, Izv. In-ta po Izucheniyu Platiny Akad. Nauk SSSR, No. 1, 29 (1929).

    Google Scholar 

  2. V. I. Goremykin, Izv. In-ta po Izucheniyu Platiny Akad. Nauk SSSR, No. 14, 41 (1937).

    Google Scholar 

  3. A. V. Babaeva and N. N. Ushakova, Zh. Neorgan. Khimii,7, 487 (1962).

    Google Scholar 

  4. A. I. Stetsenko and A. A. Grinberg, Zh. Prikl. Khimii,42, 1992 (1960).

    Google Scholar 

  5. V. I. Goremykin and K. A. Gladyshevskaya, Izv. Akad. Nauk SSSR, Otd. Khim., 108 (1943).

  6. Synthesis of Complex Compounds of Metals of the Platinum Group [in Russian], Nauka (1964).

  7. A. I. Stetsenko, Zh. Neorgan. Khimii,6, 1769 (1961).

    Google Scholar 

  8. V. I. Nefedov, M. A. Porai-Koshits, I. A. Zakharova, I. S. Kolomnikov, and N. N. Kuz'mina, Izv. Akad. Nauk SSSR, Ser. Fiz.,36, 381 (1972).

    Google Scholar 

  9. V. I. Nefedov and M. A. Porai-Koshits, Math. Res. Bull.,7, 1543 (1972).

    Google Scholar 

  10. K. Morgan and M. Jones, J. Inorg. and Nucl. Chem.,34, 259 (1972).

    Google Scholar 

  11. R. I. Novoselov, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,3, No. 7, 77 (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. I. Stetsenko, V. I. Nefedov, T. G. Abzaeva & Ya. V. Salyn'

  2. Lensovet Leningrad Technological Institute, USSR

    A. I. Stetsenko, V. I. Nefedov, T. G. Abzaeva & Ya. V. Salyn'

Authors
  1. A. I. Stetsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Nefedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. G. Abzaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya. V. Salyn'
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 530–532, March, 1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stetsenko, A.I., Nefedov, V.I., Abzaeva, T.G. et al. Complex compounds of platinum(IV) with hydroxylamine. Russ Chem Bull 23, 500–502 (1974). https://doi.org/10.1007/BF00921132

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00921132

Keywords

Search

Navigation