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Influence of geometrical isomerism on the acid properties of platinum(IV) triamines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The acid dissociation constants of rib and face triamines of the compositions [PtEnAmCln(NO2)3−n]Cl, where Am=NH3, Py and n=1, 2, were determined. In the investigated class of compounds, the influence of pyridine on the acid properties is directed: for rib triamines, more acid properties are possessed by compounds with pyridine, and for face triamines, compounds with NH3 are more acid.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    I. F. Golovaneva, T. N. Fedotova, O. N. Adrianova & P. A. Chel'tsov

Authors
  1. I. F. Golovaneva
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  2. T. N. Fedotova
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  3. O. N. Adrianova
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  4. P. A. Chel'tsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 527–530, March, 1974.

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Golovaneva, I.F., Fedotova, T.N., Adrianova, O.N. et al. Influence of geometrical isomerism on the acid properties of platinum(IV) triamines. Russ Chem Bull 23, 497–499 (1974). https://doi.org/10.1007/BF00921131

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  • DOI: https://doi.org/10.1007/BF00921131

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