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Investigation of the oxidation of VCl3 by perchlorate ions in the presence of certain complexones

  • R. P. Tishchenko
  • N. I. Perchurova
  • O. P. Ioanisiani
  • I. A. Popova
  • Vikt I. Spitsyn
Inorganic Chemistry
  • 24 Downloads

Conclusions

  1. 1.

    The composition of the complexes formed in the systems V(III)-complexone was studied by spectrophotometric and pH-metric methods; Kinst of V(III) complexonates were calculated.

     
  2. 2.

    The kinetics of the oxidation of V(III) by ClO 4 ions in the presence of ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA), was studied. In the presence of DTPA, there is less stabilization of V (III) with respect to the ClO 4 ion than in the presence of EDTA.

     

Keywords

Oxidation EDTA Perchlorate Ethylenediaminetetraacetic Acid DTPA 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • R. P. Tishchenko
    • 1
  • N. I. Perchurova
    • 1
  • O. P. Ioanisiani
    • 1
  • I. A. Popova
    • 1
  • Vikt I. Spitsyn
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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