Nitroxyl radicals with two phosphorus atoms

  • A. Sh. Mukhtarov
  • A. V. Il'yasov
  • Ya. A. Levin
  • M. S. Skorobogatova
Brief Communications

Conclusions

  1. 1.

    Nitroxyl radicals that contain two phosphorus atoms were generated by the photolysis of α-nitrosophosphonates in various solvents.

     
  2. 2.

    The mechanism of transfering the spin density to the phosphorus atom was established, and a conformation was proposed for the phosphononitroxyl.

     

Keywords

Phosphorus Photolysis Spin Density Phosphorus Atom Nitroxyl 

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Literature cited

  1. 1.
    A. L. Buchachenko and A. M. Vasserman, Stable Radicals [in Russian], Khimiya (1973).Google Scholar
  2. 2.
    Ya. A. Levin and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 477.Google Scholar
  3. 3.
    Ya. A. Levin, A. V. Il'yasov, I. D. Morozova, A. Sh. Mukhtarov, and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 314.Google Scholar
  4. 4.
    A. V. Il'yasova, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1654.Google Scholar
  5. 5.
    A. V. Il'yasov, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Teor. i Eksp. Khim.,11, 612 (1975).Google Scholar
  6. 6.
    A. Sh. Mukhtarov, A. V. Il'yasov, Ya. A. Levin, I. P. Gozman, M. S. Skorobogatova, and E. I. Zoroatskaya, Teor. i Eksp. Khim.,12, 707 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • A. Sh. Mukhtarov
    • 1
  • A. V. Il'yasov
    • 1
  • Ya. A. Levin
    • 1
  • M. S. Skorobogatova
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' BranchAcademy of Sciences of the USSRUSSR

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