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Nitroxyl radicals with two phosphorus atoms

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Nitroxyl radicals that contain two phosphorus atoms were generated by the photolysis of α-nitrosophosphonates in various solvents.

  2. 2.

    The mechanism of transfering the spin density to the phosphorus atom was established, and a conformation was proposed for the phosphononitroxyl.

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Literature cited

  1. A. L. Buchachenko and A. M. Vasserman, Stable Radicals [in Russian], Khimiya (1973).

  2. Ya. A. Levin and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 477.

  3. Ya. A. Levin, A. V. Il'yasov, I. D. Morozova, A. Sh. Mukhtarov, and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 314.

  4. A. V. Il'yasova, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1654.

  5. A. V. Il'yasov, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Teor. i Eksp. Khim.,11, 612 (1975).

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  6. A. Sh. Mukhtarov, A. V. Il'yasov, Ya. A. Levin, I. P. Gozman, M. S. Skorobogatova, and E. I. Zoroatskaya, Teor. i Eksp. Khim.,12, 707 (1976).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR

    A. Sh. Mukhtarov, A. V. Il'yasov, Ya. A. Levin & M. S. Skorobogatova

Authors
  1. A. Sh. Mukhtarov
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  2. A. V. Il'yasov
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  3. Ya. A. Levin
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  4. M. S. Skorobogatova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2816–2818, December, 1976.

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Mukhtarov, A.S., Il'yasov, A.V., Levin, Y.A. et al. Nitroxyl radicals with two phosphorus atoms. Russ Chem Bull 25, 2625–2627 (1976). https://doi.org/10.1007/BF00920915

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  • DOI: https://doi.org/10.1007/BF00920915

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