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Thermal cationotropic isomerization of 1 -trifluoroacetyl-4,6,8-trimethylazulene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

We discovered a new thermal cationotropic isomerization of 1-trifluoroacetyl-4,6,8-trimethylazulene to the 2-isomer when it is heated in 95% sulfuric acid at 195°.

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Literature cited

  1. A. G. Anderson, R. G. Anderson, and G. T. Hollander, J. Org, Chem.,30, 131 (1965).

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  2. Yu. N. Porshnev and E. M. Tereshchenko, Zh. Organ. Khim.,11, 462 (1974).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    Yu. N. Porshnev, V. I. Erikhov & M. I. Cherkashin

  2. Scientific-Research Institute of Organic Intermediates and Dyes, Moscow

    Yu. N. Porshnev, V. I. Erikhov & M. I. Cherkashin

Authors
  1. Yu. N. Porshnev
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  2. V. I. Erikhov
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  3. M. I. Cherkashin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1643–1644, July, 1976.

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Porshnev, Y.N., Erikhov, V.I. & Cherkashin, M.I. Thermal cationotropic isomerization of 1 -trifluoroacetyl-4,6,8-trimethylazulene. Russ Chem Bull 25, 1558–1559 (1976). https://doi.org/10.1007/BF00920846

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  • DOI: https://doi.org/10.1007/BF00920846

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