Conclusions
In dieneiron tricarbonyls the π-electron density in the 1 position of the coordinated butadiene system is higher than in the 2 position, while the σ-electron density is distributed uniformly.
Literature cited
N. S. Nametkin, A. I. Nekhaev, and V. D. Tyurin, Izv. Akad. Nauk SSSR, Ser. Khim., 890 (1974).
R. W. Taft, E. Price, J. R. Fox, J. C. Lewis, K. K. Andersen, and G. T. Davis, J. Am. Chem. Soc.,85, 709 (1963).
R. W. Taft, E. Price, J. R. Fox, J. C. Lewis, K. K. Andersen, and G. T. Davis, J. Am. Chem. Soc.,85, 3146 (1963).
L. G. Kuz'mina, Yu. T. Struchkov, and A. I. Nekhaev, Zh. Strukt. Khim.,13, 1115 (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1636–1638, July, 1976.
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Nametkin, N.S., Nekhaev, A.I., Gubin, S.P. et al. Induction and resonance constants of butadienyliron tricarbonyl substituents. Russ Chem Bull 25, 1552–1553 (1976). https://doi.org/10.1007/BF00920843
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DOI: https://doi.org/10.1007/BF00920843