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Oxidation of dialkyl sulfides with dimethyl sulfoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The oxidation of dibutyl sulfide with DMSO at 160–175° is complicated by secondary processes and hardly any dibutyl sulfoxide is formed.

  2. 2.

    Reaction conditions were found that made it possible to obtain certain dialkyl sulfoxides (dipropyl and dibutyl sulfoxides) in 70% yield.

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Literature cited

  1. S. Searles and H. R. Hays, J. Org. Chem.,23, 2028 (1958).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    N. K. Gusarova, G. G. Efremova, S. V. Amosova, V. A. Babkin & B. A. Trofimov

Authors
  1. N. K. Gusarova
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  2. G. G. Efremova
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  3. S. V. Amosova
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  4. V. A. Babkin
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  5. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1621–1622, July, 1976.

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Gusarova, N.K., Efremova, G.G., Amosova, S.V. et al. Oxidation of dialkyl sulfides with dimethyl sulfoxide. Russ Chem Bull 25, 1536–1537 (1976). https://doi.org/10.1007/BF00920836

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  • DOI: https://doi.org/10.1007/BF00920836

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