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Telomerization of isoprene with water and acetic acid under the influence of complex palladium catalysts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The complexes of Pd(acac)2 and Pd(OAc)2 with triphenylphosphine catalyze the telomerization of isoprene with water in the presence of CO2, which leads to the formation of isomeric dimethyloctadienols.

  2. 2.

    The complexes of Pd(acac)2 and Pd(OAc)2 with tricresyl phosphite catalyze the formation of the isomeric dimethyloctadienol acetates from isoprene and CH3COOH.

  3. 3.

    In acetone the complexes of Pd(acac)2, Pd(OAc)2 with triphenylphosphine smoothly and almost completely dimerize isoprene to 2,7-dimethyl-1,3,7-octatriene.

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Literature cited

  1. K. E. Atkins, W. E. Walker, and R. M. Manyik, Chem. Commun., 330 (1971).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin, S. A. Babich & I. V. Pisareva

Authors
  1. L. I. Zakharkin
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  2. S. A. Babich
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  3. I. V. Pisareva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1616–1617, July, 1976.

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Zakharkin, L.I., Babich, S.A. & Pisareva, I.V. Telomerization of isoprene with water and acetic acid under the influence of complex palladium catalysts. Russ Chem Bull 25, 1531–1533 (1976). https://doi.org/10.1007/BF00920834

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  • DOI: https://doi.org/10.1007/BF00920834

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