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Bis(cyclopentadienyl) compounds of zirconium with various ligands

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of bis(cyclopentadienyl)zirconium dichloride or the dibromide with the salts CF3CO2Ag, CH3CO2Na, NaBr, and LiBr leads to the mixed bis(cyclopentadienyl) compounds of Zr with various ligands in the molecule.

  2. 2.

    The reaction of Cp2ZrCl2 with excess CH3COOH in the presence of triethylamine at ∼20° gave CpZr-(OCOCH3)3.

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Literature cited

  1. A. N. Nesmeyanov et al., Methods in Heteroorganic Chemistry. Subgroup Copper, Scandium, Titanium, Vanadium, Chromium, and Manganese. Lanthanoids and Actinoids [in Russian], Vol. 1, Nauka (1974), p. 356.

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  5. L. F. Fieser and M. Fieser, Reagents for Organic Synthesis, Vol. 3, Wiley-Interscience.

  6. M. Kh. Minacheva, Dissertation, Moscow (1969).

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  8. É. M. Brainina and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim., 1118 (1973).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    É. M. Brainina & L. I. Strunkina

Authors
  1. É. M. Brainina
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  2. L. I. Strunkina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1611–1613, July, 1976.

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Brainina, É.M., Strunkina, L.I. Bis(cyclopentadienyl) compounds of zirconium with various ligands. Russ Chem Bull 25, 1527–1529 (1976). https://doi.org/10.1007/BF00920832

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  • DOI: https://doi.org/10.1007/BF00920832

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