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Mechanism of reaction for cyclocooligomerization of 2-vinylfuran with butadiene catalyzed by nickel complexes

  • U. M. Dzhemilev
  • L. Yu. Gubaidullin
  • G. A. Tolstikov
  • A. V. Spirikhin
Brief Communications

Conclusions

  1. 1.

    Using D6-butadiene, we studied the mechanism of the reaction for the cyclocooligomerization of butadiene with 2-vinylfuran in the presence of the catalyst Ni(acac)2-P(OPh)3-Al(C2H5)3.

     
  2. 2.

    The formation of 10-oxatricyclo-[9.4.0.02,9]-4,7,13-pentadecatriene proceeds via the synchronous doubling of the activated monomers without hydride transfer.

     

Keywords

Nickel Hydride Acac Butadiene Nickel Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    G. A. Tolstikov, U. M. Dzhemilev, and L. Yu. Gubaidullin, Izv. Akad. Nauk SSSR, Ser. Khim., 2158 (1974).Google Scholar
  2. 2.
    M. Orchin, Advances in Catalysis,16, 2 (1966).Google Scholar
  3. 3.
    R. Paul and S. Tchelitcheff, Bull. Soc. Chim. France, 453 (1947).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • L. Yu. Gubaidullin
    • 1
  • G. A. Tolstikov
    • 1
  • A. V. Spirikhin
    • 1
  1. 1.Institute of ChemistryBashkir Branch of the Academy of Sciences of the USSRUfa

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