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Use of IR spectroscopy to study donor-acceptor interactions between phosphoryl compounds and antimony trichloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have used IR spectroscopy to study phosphoryl compound + SbCl3 + CCl4 systems, determining equilibrium constants, enthalpies of complex formation, and the accompanying. PCνP=O shifts.

  2. 2.

    Inductive effects from the phosphorous substituents are more significant here than the stability of the donor -acceptor complex.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    L. Kh. Ashrafullina, V. E. Bel'skii & R. R. Shagidullin

Authors
  1. L. Kh. Ashrafullina
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  2. V. E. Bel'skii
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  3. R. R. Shagidullin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, no. 7, pp. 1504–1506, July.

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Ashrafullina, L.K., Bel'skii, V.E. & Shagidullin, R.R. Use of IR spectroscopy to study donor-acceptor interactions between phosphoryl compounds and antimony trichloride. Russ Chem Bull 25, 1435–1437 (1976). https://doi.org/10.1007/BF00920813

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  • DOI: https://doi.org/10.1007/BF00920813

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