Advertisement

Acid catalysis in radical hydroperoxide decomposition

  • V. M. Solyanikov
  • T. A. Videneeva
  • N. N. Zhidkova
Physical Chemistry
  • 35 Downloads

Conclusions

  1. 1.

    Acid catalysis of radical hydroperoxide decomposition can occur in various types of polar solutions (acetic acid, methyl ethyl kentone, isopropanol).

     
  2. 2.

    There is a correlation between the acid strength and the activity in catalyzing radical breakdown.

     
  3. 3.

    Cumyl hydroperoxide decomposes with the formation of free radicals under the action of hydrochloric acid. The radical decomposition mechanism contributes to the extent of 0.18% of the overall decomposition.

     

Keywords

Methyl Acetic Ethyl Acetic Acid Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. G. Privalova and Z. K. Maizus, Izv. Akad. Nauk SSSR, Ser. Khim., 28 (1964).Google Scholar
  2. 2.
    V. L. Antonovskii, E. T. Denisov, and L. V. Solntseva, Kinet. Katal.,7, 409 (1966).Google Scholar
  3. 3.
    V. M. Solyanikov and E. T. Denisov, Dokl. Akad. Nauk SSSR,173, 1106 (1967).Google Scholar
  4. 4.
    V. M. Solyanikov and E. T. Denisov, Neftekhimiya,9, 11 (1969).Google Scholar
  5. 5.
    V. M. Solyanikov and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1391 (1968).Google Scholar
  6. 6.
    J. Hopkins, Organic Hydroperoxides [Russian translation], Khimiya, Moscow-Leningrad (1964), p. 445.Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • V. M. Solyanikov
    • 1
  • T. A. Videneeva
    • 1
  • N. N. Zhidkova
    • 1
  1. 1.Chernogolovka Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

Personalised recommendations