Conclusions
-
1.
Flames resulting from chain NCl3 decomposition are propagated through NCl3 + He mixtures lying outside the autoignition region.
-
2.
The fact that these are essentially isothermal flames is an indication of the important role of positive chain interaction in this process.
Similar content being viewed by others
Literature cited
V. V. Azatyan, R. R. Borodulin, and E. A. Markevich, Kinet. Katal.,15, 1610 (1976).
R. R. Borodulin, E. A. Markevich, V. V. Azatyan, and N. N. Semenov, Kinet. Katal.,17, No. 4 (1976).
A. Ya. Apin, Zh. Fiz. Khim.,14, 494 (1940).
N. N. Semenov, Certain Problems in Chemical Kinetics and Reactivity [in Russian], Izd. Akad. Nauk SSSR (1958).
V. V. Azatyan, R. R. Borodulin, E. A. Markevich, N. M. Rubtsov, and N. N. Semenov, Dokl. Akad. Nauk SSSR,224, 1096 (1975).
T. C. Clark and M. A. A. Clyne, Trans. Faraday Soc.,68, 372 (1970).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1459–1461, July, 1976.
Rights and permissions
About this article
Cite this article
Azatyan, V.V., Borodulin, R.R., Markevich, E.A. et al. Isothermal propagation of rarefied nitrogen trichloride flames. Russ Chem Bull 25, 1396–1397 (1976). https://doi.org/10.1007/BF00920803
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00920803