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Complexing properties of the trifluoroethyl xanthate ion and volatility of its intracomplex compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have synthesized KS2COCH2CF3, Ni(S2COCH2CF3)2, Pd(S2COCH2CF3)2, and Co(S2COCH2-CF3)3 and have characterized the IR and electron spectra.

  2. 2.

    The complexes completely sublime at a pressure of 3–5 · 10−2 mm and at temperatures in the ranges 70–75°C (cobalt chelate) and 90–95°C (nickel and palladium chelates).

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk

    S. V. Larionov & L. A. Kosareva

Authors
  1. S. V. Larionov
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  2. L. A. Kosareva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1451–1455, July, 1976.

We thank I. M. Cheremisina for recording the high-frequency IR spectra.

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Larionov, S.V., Kosareva, L.A. Complexing properties of the trifluoroethyl xanthate ion and volatility of its intracomplex compounds. Russ Chem Bull 25, 1388–1391 (1976). https://doi.org/10.1007/BF00920801

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  • DOI: https://doi.org/10.1007/BF00920801

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