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Mechanism of isoprene hydrogenation on palladium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction for the selective hydrogenation of isoprene on a palladium catalyst at low temperatures is accomplished mainly on a small portion of the surface via the rapid formation of the surface isoprene compound in the undissociated form, with the subsequent slow steps of its conversion to the semihydrogenated form, and then to isopentenes.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Z. T. Beisembaeva, B. S. Gudkov, M. S. Kharson, N. I. Popov & S. L. Kiperman

Authors
  1. Z. T. Beisembaeva
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  2. B. S. Gudkov
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  3. M. S. Kharson
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  4. N. I. Popov
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  5. S. L. Kiperman
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 949–951, April, 1975.

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Beisembaeva, Z.T., Gudkov, B.S., Kharson, M.S. et al. Mechanism of isoprene hydrogenation on palladium. Russ Chem Bull 24, 863–865 (1975). https://doi.org/10.1007/BF00920713

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  • DOI: https://doi.org/10.1007/BF00920713

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