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Effect of type of a luminosilicate support for Co catalyst on the initiating effect of carbon monoxide in the hydropolymerization of ethylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The course of the ethylene hydropolymerization reaction at 190 and 70°, respectively, initiated by 5 and 0.01% CO, depends to a substantial degree on the type of aluminosilicate support for the Co catalyst.

  2. 2.

    In general, both the yield of the hydropolymerization products and its selectivity with respect to hydrocarbons with a high molecular weight change in the same manner as the SiO2 /Al2O3 mole ratio in the aluminosilicate support.

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Literature cited

  1. Ya. T. Éidus, N. I. Ershov, K. V. Puzitskii, and I. V. Guseva, Izv. Akad. Nauk SSSR, Otd. Khim., Nauk, 120, 331, 913 (1960).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Ya. T. Éidus, Khoang Chong Iem & N. I. Ershov

Authors
  1. Ya. T. Éidus
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  2. Khoang Chong Iem
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  3. N. I. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 937–939, April, 1975.

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Éidus, Y.T., Iem, K.C. & Ershov, N.I. Effect of type of a luminosilicate support for Co catalyst on the initiating effect of carbon monoxide in the hydropolymerization of ethylene. Russ Chem Bull 24, 850–852 (1975). https://doi.org/10.1007/BF00920709

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  • DOI: https://doi.org/10.1007/BF00920709

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