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13C NMR study of geometric isomers of hydrocarbons of tricyclo[5.2.1.02,6]decane series

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the parameters of the13C NMR spectra of the exo- and endo-isomers of hydrocarbons of the tricyclo[5.2.1.02,6]decane series and related compounds.

  2. 2.

    The spatial arrangement of the cyclopentane ring in tricyclo[5.2.1.02,6]decane exerts the strongest influence on the chemical shift of the bridge carbon of the norbornane part of the molecule.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. S. Murakhovskaya, A. U. Stepanyants, K. I. Zimina, O. A. Aref'ev & V. I. Epishev

  2. Institute of Geology and Development of Fuel Deposits, Academy of Sciences of the USSR, Moscow

    A. S. Murakhovskaya, A. U. Stepanyants, K. I. Zimina, O. A. Aref'ev & V. I. Epishev

Authors
  1. A. S. Murakhovskaya
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  2. A. U. Stepanyants
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  3. K. I. Zimina
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  4. O. A. Aref'ev
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  5. V. I. Epishev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 933–936, April, 1975.

The authors are deeply indebted to Al. A. Petrov for his interest in the work and valuable discussion.

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Murakhovskaya, A.S., Stepanyants, A.U., Zimina, K.I. et al. 13C NMR study of geometric isomers of hydrocarbons of tricyclo[5.2.1.02,6]decane series. Russ Chem Bull 24, 847–849 (1975). https://doi.org/10.1007/BF00920708

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  • DOI: https://doi.org/10.1007/BF00920708

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