Skip to main content
SpringerLink
Log in

Electron-donor properties and energy of pπ-conjugation of a series of substituted diphenyl ethers

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The thermal effects of the reactions of complex formation and the dipole moments of complexes of AlBr3 with bromo-, methyl-, methoxy-, and phenoxy-substituted diphenyl ethers (DE) were measured. A correlation of the complex-forming ability of the DE with the Hammettσ-constants was established.

  2. 2.

    The energies of pπ-conjugation of the investigated ethers were determined.

  3. 3.

    The model D′, presupposing free but interrelated rotation of the phenyl rings around the C-O bond, is the most probable for substituted DE.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. I. P. Romm and E. N. Gur'yanova, Zh. Obshch. Khimii,38, 1297 (1968); I. P. Romm, E. N. Guryanova, and K. A. Kocheshkov, Tetrahedron,25, 2455 (1969).

    Google Scholar 

  2. I. P. Romm, V. V. Kopylov, and E. N. Gur'yanova, Zh. Struk. Khimii,11, 671 (1970).

    Google Scholar 

  3. V. V. Kopylov, I. P. Romm, E. N. Gur'yanova, and A. N. Pravednikov, Zh. Obshch. Khimii,44, 1980 (1974).

    Google Scholar 

  4. I. P. Gol'dshtein, E. N. Gur'yanova, and I. R. Karpovich, Zh. Fiz. Khimii,39, 932 (1965).

    Google Scholar 

  5. E. N. Gur'yanova and I. P. Gol'dshtein, Zh. Obshch. Khimii,32, 12 (1962).

    Google Scholar 

  6. Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Izd. Rostovsk. Un-ta (1966), pp. 85, 192.

  7. M. Gomel, M. Lumbroso, N. Marziano, and R. Passerini, Bull. Chim. France, 1908 (1959).

  8. R. J. W. Le Fevre and J. D. Saxby, J. Chem. Soc., B, 1064 (1966).

    Google Scholar 

  9. I. A. Bogdanov and M. F. Vuks, Vestn. Leningr. Un-ta, Ser. Fiz. i Khim., No. 16, 46 (1965).

    Google Scholar 

  10. C. Garrigou-Lagrange, M. Horak, R. K. Khanna, and E. R. Lippincott, Collect. Czechoslov. Chem. Comm.,35, 3230 (1970).

    Google Scholar 

  11. K. Higasi, Dipole, Molecule, and Chemistry, Monograph Series of the Research Institute of Applied Electricity, Sapporo (1965), p. 13.

  12. V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov, Dipole Moments in Organic Chemistry [in Russian], Khimiya, Leningrad (1968), pp. 79, 87.

    Google Scholar 

  13. O. A. Osipov, V. N. Minkin, and A. D. Garnovskii, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1971).

Download references

Author information

Authors and Affiliations

  1. L. Ya. Karpov Physicochemical Institute, Moscow

    I. P. Romm, V. V. Kopylov, E. N. Gur'yanova, A. N. Pravednikov & K. A. Kocheshkov

Authors
  1. I. P. Romm
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Kopylov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Gur'yanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Pravednikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. A. Kocheshkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 828–834, April, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Romm, I.P., Kopylov, V.V., Gur'yanova, E.N. et al. Electron-donor properties and energy of pπ-conjugation of a series of substituted diphenyl ethers. Russ Chem Bull 24, 747–752 (1975). https://doi.org/10.1007/BF00920687

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00920687

Keywords

Search

Navigation