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Investigation of the nuclear quadrupole resonance spectra of5Mn,185Re,187Re, and127I of derivatives of manganese and rhenium cyclopentadienyltricarbonyls

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The NQR185Re,187Re,55Mn, and127I spectra of a number of derivatives of manganese and rhenium cyclopentadienyltricarbonyls were investigated.

  2. 2.

    The change in the quadrupole coupling constant on the metal atom is due to a greater degree to conjugation characteristics of the substituents than to induction characteristics; moreover, in rhenium derivatives this sensitivity is approximately an order of magnitude higher than in manganese derivatives.

  3. 3.

    The higher NQR127I frequencies in (CO)3ReC5H4I than in (CO)3MnC6H4I permit us to consider the (CO3)ReC5H4— group as a stronger electron acceptor than (CO)3MnC5H4-.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    E. V. Bryukhova, G. K. Semin, I. M. Alymov, S. I. Kuznetsov, K. N. Anisimov, N. E. Kolobova & Yu. V. Makarov

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  1. E. V. Bryukhova
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  2. G. K. Semin
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  3. I. M. Alymov
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  4. S. I. Kuznetsov
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  5. K. N. Anisimov
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  6. N. E. Kolobova
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  7. Yu. V. Makarov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 797–801, April, 1975.

The authors would like to express their gratitude to A. N. Nesmeyanov for his interest in the work.

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Bryukhova, E.V., Semin, G.K., Alymov, I.M. et al. Investigation of the nuclear quadrupole resonance spectra of5Mn,185Re,187Re, and127I of derivatives of manganese and rhenium cyclopentadienyltricarbonyls. Russ Chem Bull 24, 719–722 (1975). https://doi.org/10.1007/BF00920681

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  • DOI: https://doi.org/10.1007/BF00920681

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