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Investigation of β, β-dichlorovinyl ketones by the method of nuclear quadrupole resonance

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The NQR-35Cl spectra of a series ofβ,β-dichlorovinylketones exhibit a linear dependence of the NQR-35Cl frequencies on theσ-parameters of the substituents. The behavior of the NQR frequencies of the halogens is significantly influenced by the conformation of the C12C=CHCOR molecule.

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Literature cited

  1. G. A. Gavrilova, G. G. Levkovskaya, A. N. Mirskova, and Yu. L. Frolov, Summaries of the Eighth Siberian Conference on Spectroscopy [in Russian], Irkutsk. In-t Org. Khimii (1972), p. 48.

  2. G. K. Semin, T. A. Babushkina, and G. G. Yakobson, The Use of Nonlinear Quadrupole Resonance in Chemistry [in Russian], Khimiya (1972).

  3. Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Izd. Rostovsk. Gos. Un-ta (1967).

  4. C. Townes and B. Daily, J. Chem. Phys.,17, 782 (1949).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    G. G. Levkovskaya, A. N. Mirskova, E. V. Bryukhova, V. P. Kazakov & A. S. Atavin

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    G. G. Levkovskaya, A. N. Mirskova, E. V. Bryukhova, V. P. Kazakov & A. S. Atavin

Authors
  1. G. G. Levkovskaya
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  2. A. N. Mirskova
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  3. E. V. Bryukhova
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  4. V. P. Kazakov
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  5. A. S. Atavin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 793–797, April, 1975.

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Levkovskaya, G.G., Mirskova, A.N., Bryukhova, E.V. et al. Investigation of β, β-dichlorovinyl ketones by the method of nuclear quadrupole resonance. Russ Chem Bull 24, 715–718 (1975). https://doi.org/10.1007/BF00920680

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  • DOI: https://doi.org/10.1007/BF00920680

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