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Deactivation of inhibitors (nitric oxide, alkylnitriles) in the interaction with the monomer (methyl methacrylate)

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The polymerization of methyl methacrylate, inhibited by NO, was investigated. The weak inhibiting action of NO is due to an interaction between the monomer and inhibitor, leading to the formation of a nitronitroso derivative of methyl methacrylate. The latter was isolated and identified.

  2. 2.

    An analogous effect of deactivation of inhibitors in the interaction with the monomer is also observed in the polymerization of methyl methacrylate in the presence of alkyl nitrites as a result of the formation of an alkyl nitrite-methyl methacrylate molecular complex.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    G. V. Leplyanin, L. F. Antonova, S. R. Rafikov, R. R. Faizullov, E. E. Zaev, V. A. Ponomareva & Yu. G. Grechishnikov

Authors
  1. G. V. Leplyanin
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  2. L. F. Antonova
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  3. S. R. Rafikov
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  4. R. R. Faizullov
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  5. E. E. Zaev
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  6. V. A. Ponomareva
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  7. Yu. G. Grechishnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 754–757, April, 1975.

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Leplyanin, G.V., Antonova, L.F., Rafikov, S.R. et al. Deactivation of inhibitors (nitric oxide, alkylnitriles) in the interaction with the monomer (methyl methacrylate). Russ Chem Bull 24, 677–680 (1975). https://doi.org/10.1007/BF00920672

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  • DOI: https://doi.org/10.1007/BF00920672

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