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Peculiarities of the interaction of CO with copper cations in zeolites according to the data of the ESR and IR spectra

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The state of the Cu2+ cations in the zeolite framework has a decisive influence on the nature of their interaction with CO.

  2. 2.

    Isolated Cu2+ cations in zeolites do not interact with CO in the interval from −196 to 500°.

  3. 3.

    Weak magnetic associates of Cu2+ cations in zeolites in the interval from −100 to −196° form adsorption complexes with CO, and at 300 to 500° they oxidize CO to CO2 and are reduced to Cu+ cations. The latter processes evidently occur with the participation of nonskeletal oxygen of the hydroxyls in the coordination sphere of the Cu2+ cations, entering into the composition of the weak magnetic associates.

  4. 4.

    Strong associates of Cu2+ cations, including a nonskeletal bridge oxygen, oxidize CO to CO2 and carbonates even at low temperatures. The catalytic activity of CuY zeolites in the oxidation of CO is caused by the presence of strong magnetic associates of Cu2+ cations in them.

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Literature cited

  1. C. M. Naccache and Y. Ben Taarit, J. Catalysis,22, 171 (1971).

    Google Scholar 

  2. T. A. Bregadze, V. A. Seleznev, A. A. Kadushin, and O. V. Krylov, Izv. Akad. Nauk SSSR, Ser. Khim., 2701 (1973).

  3. H. Bremer, W. Morke, D. Schodel, and E. Vogt, Advances Chem. Series,121, 249 (1973).

    Google Scholar 

  4. Y. Y. Huang and E. F. Vansant, J. Phys. Chem.,77, 663 (1973).

    Google Scholar 

  5. Y. Y. Huang, J. Catalysis,30, 187 (1973).

    Google Scholar 

  6. N. G. Maksimov, V. F. Anufrienko, and K. G. Ione, Zh. Strukt. Khimii,13, 1020 (1972).

    Google Scholar 

  7. N. G. Maksimov, K. G. Ione, V. F. Anukfrienko, P. N. Kuznetsov, N. N. Bobrov, and G. K. Boreskov, Dokl. Akad. Nauk SSSR,217, 135 (1974).

    Google Scholar 

  8. L. Little, Infrared Spectra of Adsorbed Molecules [Russian translation], Mir (1969).

  9. A. A. Shklyaev, Dissertation [in Russian], Novosibirsk (1973).

  10. C. L. Angell and P. C. Shaffer, J. Phys. Chem.,70, 1413 (1966).

    Google Scholar 

  11. T. A. Egerton, A. Kagan, F. S. Stone, and J. C. Vickerman, J. Chem. Soc., Faraday Trans.,68, 723 (1972).

    Google Scholar 

  12. T. A. Egerton and J. C. Vickerman, J. Chem. Soc., Faraday Trans.,69, 39 (1973).

    Google Scholar 

  13. O. V. Al'tshuler, I, A. Tsitovskaya, O. M. Vinogradova, and V. A. Seleznev, Izv. Akad. Nauk SSSR, Ser. Khim., 2145 (1972).

  14. K. G. Ione, N. N. Bobrov, G. K. Boreskov, and L. A. Vostrikova, Dokl. Akad. Nauk SSSR,210, 388 (1973).

    Google Scholar 

  15. N. G. Maksimov, V. F. Anufrienko, and K. G. Ione, Dokl. Akad. Nauk SSSR,212, 142 (1973).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    N. N. Bobrov, A. A. Davydov, N. G. Maksimov, K. G. Ione & V. F. Anufrienko

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  1. N. N. Bobrov
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  2. A. A. Davydov
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  3. N. G. Maksimov
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  4. K. G. Ione
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  5. V. F. Anufrienko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 748–753, April, 1975.

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Bobrov, N.N., Davydov, A.A., Maksimov, N.G. et al. Peculiarities of the interaction of CO with copper cations in zeolites according to the data of the ESR and IR spectra. Russ Chem Bull 24, 672–676 (1975). https://doi.org/10.1007/BF00920671

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  • DOI: https://doi.org/10.1007/BF00920671

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