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Calculation of the kinetic parameters for reactions of electron transfer between aromatic hydrocarbons and their anion radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A formula was obtained for the energy of reorganization of the solvent in reactions of electron transfer between nonspherical reagents.

  2. 2.

    The kinetic parameters (preexponential factors and activation energies) were calculated for cesses of electron transfer between aromatic molecules and their ion radicals. The values obtained were compared with the experimental data.

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Literature cited

  1. K. Suga and S. Aoyagui, Bull. Chem. Soc., Japan,46, 755 (1973).

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  2. R. A. Marcus, J. Chem. Phys.,24, 966 (1956).

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  3. R. R. Dogonadze and A. M. Kuznetsov, Results of Science. Physical Chemistry. Kinetics [in Russian], Vol. 2, VINITI (1973).

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  5. E. Yanke and F. Emde, Tables of Functions [in Russian], Gostekhizdat (1948).

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    É. D. German, V. G. Dvali & R. R. Dogonadze

  2. Institute of General and Inorganic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    É. D. German, V. G. Dvali & R. R. Dogonadze

Authors
  1. É. D. German
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  2. V. G. Dvali
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  3. R. R. Dogonadze
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 742–747, April, 1975.

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German, É.D., Dvali, V.G. & Dogonadze, R.R. Calculation of the kinetic parameters for reactions of electron transfer between aromatic hydrocarbons and their anion radicals. Russ Chem Bull 24, 667–671 (1975). https://doi.org/10.1007/BF00920670

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  • DOI: https://doi.org/10.1007/BF00920670

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