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Some reactions of trichloromethyl and 3, 3-dichloroallyl compounds of mercury

  • R. Kh. Freidlina
  • F. K. Velichko
Article
  • 16 Downloads

Summary

  1. 1.

    Trichloromethyl compounds of mercury react with hydrogen cyanide, potassium cyanide and potassium iodide as inorganic mercury salts. They behave as typical organomercury compounds towards alkali and diazomethane. Trichloromethyl compounds of mercury react with a Grignard reagent in two ways — as salts and as organomercury compounds.

     
  2. 2.

    Bromotrichloromethane reacts with sodium amalgam to give trichloromethylmercuric bromide and not bis -trichloromethylmercury.

     
  3. 3.

    1,1-Dichloro-3-iodo-2-methylpropene-l was converted to 1,1-dichloro-3-iodomercuri-2-methylpropene-1. Some of its chemical properties were studied.

     

Keywords

Hydrogen Sodium Potassium Mercury Bromide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau Enterprises, Inc. 1960

Authors and Affiliations

  • R. Kh. Freidlina
    • 1
  • F. K. Velichko
    • 1
  1. 1.Institute of Heteroorganic Compounds Academy of Sciences USSRUSSR

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