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Use of oxidation-reduction systems for the initiation of 1-octene with carbon tetrachloride

  • R. Kh. Friedlina
  • E. Ts. Chukovskaya
Organic and Biological Chemistry

Summary

  1. 1.

    Oxidation-reduction systems containing benzoyl peroxide and an organic reducing agent initiate addition and telomerization reactions of 1-octene with carbon tetrachloride at 25–45‡. The following were used as organic reducing agents: hydroxymethyl p-tolyl sulfone, triethanolamine, and dibutyl phosphite.

     
  2. 2.

    The use of additions of iron and copper compounds to the benzoyl peroxide — hydroxymethyl p-tolyl sulfone system makes it possible to increase the yields of products and to carry out the reaction at room temperature.

     

Keywords

Copper Tetrachloride Carbon Tetrachloride Benzoyl Hydroxymethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • R. Kh. Friedlina
    • 1
  • E. Ts. Chukovskaya
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of SciencesUSSR

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