Use of oxidation-reduction systems for the initiation of 1-octene with carbon tetrachloride

  • R. Kh. Friedlina
  • E. Ts. Chukovskaya
Organic and Biological Chemistry


  1. 1.

    Oxidation-reduction systems containing benzoyl peroxide and an organic reducing agent initiate addition and telomerization reactions of 1-octene with carbon tetrachloride at 25–45‡. The following were used as organic reducing agents: hydroxymethyl p-tolyl sulfone, triethanolamine, and dibutyl phosphite.

  2. 2.

    The use of additions of iron and copper compounds to the benzoyl peroxide — hydroxymethyl p-tolyl sulfone system makes it possible to increase the yields of products and to carry out the reaction at room temperature.



Copper Tetrachloride Carbon Tetrachloride Benzoyl Hydroxymethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    C. Walling, Free Radicals in Solution [Russian translation], IL, Moscow, p. 447 (1960).Google Scholar
  2. 2.
    M. Asscher, D. Vofsi, J. Chem. Soc. 2261 (1961).Google Scholar
  3. 3.
    M. Asscher, D. Vofsi, Chem. and Ind. 209 (1962).Google Scholar
  4. 4.
    B. A. Bulstein, J. Amer. Chem. Soc.83, 100 (1961); U. S. Pat. 2971970; Chem. Abstrs.55, 12356 (1961).Google Scholar
  5. 5.
    H. Huemer, H. Schulz, U. S. Pat. 2768196 (1956); German Fed. Repub. Pat. 972796 (1959). RZhKhim, 9188 (1961).Google Scholar
  6. 6.
    L. Speier, J. A. Webster, J. Organ. Chem.21, 1044 (1956).Google Scholar
  7. 7.
    M. S. Kharasch, E. V. Jensen, W. H. Urry, J. Amer. Chem. Soc.69 1100 (1947); Science102, 128 (1945).Google Scholar
  8. 8.
    U. S. Pat. 2857365 (1958); Chem. Abstrs.53, 1853 (1959).Google Scholar
  9. 9.
    H. Bredereck, E. BÄder, A. Wohnhas, Makromolek. Chem.12, 100 (1954); H. Bredereck, E. BÄder, A. Wohnhas, W. Nübling, U. S. Pat. 2779751: Chem. Abstrs.51, 9214 (1957); H. Bredereck, E. BÄder, U. S. Pat. 2846418; Chem. Abstrs.52, 21234 (1958); H. Bredereck, E. BÄder, W. Nübling, U. S. Pat. 2776952; Chem. Abstrs.51, 6227 (1957); G. M. Brauer, F. R. Burns, J. Polymer Sci.19, 311 (1956); British Pat. 790320; Chem. Abstrs.52, 21231 (1959); Swiss Pat. 334648; Chem. Abstrs.53, 16592 (1959).Google Scholar
  10. 10.
    B. A. Kazanskii, A. A. Liberman, A. F. PlatÉ, M. I. Rozengart and G. A. Tarasova, Zh. obshch. khimii 1507 (1947).Google Scholar
  11. 11.
    H. Bredereck, E. BÄder, Ber.87, 129 (1954).Google Scholar
  12. 12.
    R. Kh. Freidlina, É. M. Brainina and A. N. Nesmeyanov, Izv. AN SSSR, Otd. khim. n. 59, (1960).Google Scholar
  13. 13.
    F. Gash, Montash. Chem.21, 98 (1901).Google Scholar

Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • R. Kh. Friedlina
    • 1
  • E. Ts. Chukovskaya
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of SciencesUSSR

Personalised recommendations