Summary
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1.
1,5-Diketones are the first products of the hydrogenolysis of 2-alkyl-5-acylfurans on platinized carbon or platinized asbestos at. 200–300‡ and atmospheric pressure.
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2.
A method was proposed for the catalytic synthesis of 1,5-diketones from 2-alkyl-5-acylfurans.
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N. I. Shuikin and I. F. Bel'skii, Doklady Akad. Nauk SSSR127, 359 (1959).
N. I. Shuikin, I. F. Bel'skii, and G. K. Vasilevskaya, Doklady Akad. Nauk SSSR132, 861 (1960).
A. L. Mndzhoyan, Syntheses of Heterocyclic Compounds [in Russian] (Bull. Acad. Sci. Armenian SSR, Erevan, 1958) No. 2, p. 14.
R. G. Fargher and W. H. Perkin, J. Chem. Soc.105, 1353 (1914).
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Shuikin, N.I., Bel'skii, I.F. & Vasilevskaya, G.K. The catalytic synthesis of 1.5-diketones. Russ Chem Bull 10, 334–335 (1961). https://doi.org/10.1007/BF00919578
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DOI: https://doi.org/10.1007/BF00919578