Summary
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1.
On the basis of a study of the infrared and ultraviolet absorption spectra of the nitroalkanes and a systematization of the data in the literature, the possibility of identifying mononitroalkanes, gem-dinitroalkanes and 1,1,1-trinitroalkanes by spectroscopic methods was demonstrated.
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2.
By means of infrared spectroscopy the reciprocal influence of the nitro group and hydrocarbon radicals in nitroalkanes containing one, two or three nitro groups on the end carbon atom was discovered.
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S. S. Novikov, V, M. Belikov, A. A. Fainzil'berg, L. V. Ershova, V. I. Slovetskii, and S. A. Shevelev, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk1959, 1855.
J. Brown, J. Amer. Chem. Soc.77, 6341 (1955).
R. Haszeldine, J. Chem. Soc.1953, 2525.
D. Smith, C. Pan, and J. Nilson, J. Chem. Phys.18, 706 (1950).
E. Plyler and T. Burdine. Phys. Rev. (2)35, 605 (1930).
U. Lenormant and P. Glement, Bull.1946, 559.
F. Halverson, Rev. Modern Phys.19, 87 (1947).
S. Bogdan and D. Sefanescu, Chem. Abstrs.37, 3668 (1943); Bull. Soc. romaine phys.42, 73 (1941).
A. Wells and E. Nilson, J. Chem. Phys.9, 314 (1941).
R. Pierson, A. Fletcher, and E. Gantz, Analyt. Chem.28, 1218 (1956).
Randel, Fouler, Fuson, and Danyl, Infrared Determination of Organic Structure, N. Y. 1949, p. 20.
T. Wilson, J. Chem. Phys.11, 361 (1943).
T. Urbanskii, Byulleten' Pol'skoi Akademii nauk, otd. 3, t. 4, No. 6 (1956) p. 371.
N. Kornblum, H. Ungnade, and R. Smiley, J. Organ. Chem.21, 377 (1956).
M. Bender and J. Figneras, J. Amer. Chem. Soc.75, 6304 (1953).
J. Mathieu and D. Massignon, Ann. Phys.16, 5 (1941).
J. Mathieu and D. Massignon, Compt. rend.211, 783 (1940).
J. Mathieu and D. Massignon, Compt. rend.212, 1084 (1941).
H. Ungnade and L. Kissinger, J. Organ. Chem.22, 1088 (1957).
C. Grabiel, D. Bisgrove, and L. Clapp, J. Amer. Chem. Soc.77, 1293 (1955).
N. Sheppard and D. Simpson, Quart. Rev.7, 19 (1953).
J. Linnett, Trans. Faraday Soc.41, 223 (1945).
T. Urbanski, Roszn. Chem.29, 11 (1955).
N. Bayliss and E. McRae, J. Phys. Chem.58, 1006 (1954).
N. Bayliss and C. Brackenridge, J. Amer. Chem. Soc.77, 3959 (1955).
H. Ungnade and R. Smiley, J. Organ. Chem.21, 993 (1956).
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Slovetskii, V.I., Shlyapochnikov, V.A., Shevelev, S.A. et al. Molecular absorption spectra of nitroalkanes. Russ Chem Bull 10, 303–309 (1961). https://doi.org/10.1007/BF00919571
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DOI: https://doi.org/10.1007/BF00919571