Summary
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1.
1,7-Diphenyl-4-(3-phenylpropyl) heptane, 1,7-dicyclohexyl-4-(3-cyclohexylpropyl)heptane, 1,1,1-tritolylheptane, 1,1,1-tricyclohexylheptane, and 1,7-diphenyl-4-(2-cyclohexylethyl)heptane were prepared for the first time by organomagnesium synthesis.
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2.
The following hydrocarbons were obtained by selective hydrogenation of the corresponding triphenylalkanes over PtO2: 1,7-diphenyl-4-(3-cyclohexylpropyl)heptane, 1,5-diphenyl-3-(2-cyclohexylethyl)pentane, 1-phenyl-4,7-dicyclohexylheptane, 1-phenyl-4-(2-cyclohexylpropyl)decane, 1-cyclohexyl-4-(3-cyclohexylpropyl)decane, 1-phenyl-3-(2 -cyclohexylethyl)tridecane, and 1-phenyl-4-(2-phenylethyl)-7-cyclohexylheptane.
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R. Adams, in the collection: Syntheses of Organic Preparations [Russian translation] (IL, 1949) Vol. 1, p. 357.
R. W. Schiessler, D. G. Clarke, C. S. Rowland, W. S. Sloatman, and C. H. Herr, Refiner22, 390 (1943).
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In conclusion, the authors would like to thank Yu. P. Egorov and E. Lubush for plotting the spectra.In conclusion, the authors would like to thank Yu. P. Egorov and E. Lubush for plotting the spectra.
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Chel'tsova, M.A., Petrov, A.D. & Grigos, V.I. Synthesis and properties of DI-and triphenylalkanes. Russ Chem Bull 10, 270–276 (1961). https://doi.org/10.1007/BF00919565
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DOI: https://doi.org/10.1007/BF00919565