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Kinetics of the oxidation of isobutane in the presence of hydrogen bromide

  • A. A. Babaeva
  • Z. K. Maizus
  • N. M. Émanuél'
Article
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Summary

  1. 1.

    We have investigated the kinetics of isobutane oxidation, In the presence of HBr in terms of the consumption of i-C4H1, O1, and HBr and the formations of ten-butyl hydroperoxide, tert-butyl alcohol, acetone, CO,and CO1.

     
  2. 2.

    We have clearly demonstrated that the process occurs in stages, i.e., macroscopic stages separate in time. The first stage consists in the oxidation of isobutane, mainly to tert-butyl hydroperoxide. Oxygen is no longer consumed in the second stage, and isobutane is oxidized by tert-butyl hydroperoxide to tert-butyl alcohol, the hydroperoxide being converted to acetone.

     

Keywords

Oxidation Oxygen Hydrogen Alcohol Acetone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1960

Authors and Affiliations

  • A. A. Babaeva
    • 1
    • 2
  • Z. K. Maizus
    • 1
    • 2
  • N. M. Émanuél'
    • 1
    • 2
  1. 1.Institute of Chemical Physics of the Academy of Sciences of the USSRUSSR
  2. 2.The M. V. Lomonosov Moscow State UniversityUSSR

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