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Raman-spectrum investigation of the conformations of cis-and trans-1,3-dimethylcyclohexanols

  • M. I. Batuev
  • A. A. Akhrem
  • A. V. Kamernitskii
  • A. D. Matveeva
Brief Communications

Summary

When configurations are named with respect to the actually largest substituents, the preferred conformation for the compound (I) in the liquid phase is trans-1e3a, and for compound (II) in the liquid phase cis-1e3e with equatorial hydrogen-bonded hydroxyls; when this nomenclature, based on the actually largest substituents is used, the Auwers-Sktta rule is not reversed for the compounds (I) and (II) in the liquid state.

Keywords

Hydroxyl Liquid Phase Liquid State Prefer Conformation Large Substituent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. [1]
    A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 748 (1959).Google Scholar
  2. [2]
    M. I. Batuev, J. Phys. Chem. 23, 1399 (1949); 24, 381 (1950); 21, 137 (1947); 25, 884 (1951); Bull. Acad. Sci. USSR, Physics Series II, 336 (1947); 14, 429 (1950).Google Scholar
  3. [3]
    M. I. Batuev, A. A. Akhrem, A. D. Matveeva, and I. N. Nazarov, Proc. Acad. Sci. USSR, 117, 423 (1957); Bull. Acad. Sci. USSR, Div. Chem. Sci. 1389 (1958); M. I. Batuev, A. A. Akhrem, A. D. Matveeva, A. V. Kamernitskii, and I. N. Nazarov, Proc. Acad. Sci. USSR, 120,779 (19585; Bull. Acad. Sci. USSR, Div. Chem. Sci. 556 (1959). M. I. Batuev, A. A. Akhrem, and A. D. Matveeva, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1665 (1959).Google Scholar

Copyright information

© Consultants Bureau 1960

Authors and Affiliations

  • M. I. Batuev
    • 1
    • 2
  • A. A. Akhrem
    • 1
    • 2
  • A. V. Kamernitskii
    • 1
    • 2
  • A. D. Matveeva
    • 1
    • 2
  1. 1.Institute of Mineral FuelsUSSR
  2. 2.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

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