Raman-spectrum investigation of the conformations of cis-and trans-1,3-dimethylcyclohexanols

  • M. I. Batuev
  • A. A. Akhrem
  • A. V. Kamernitskii
  • A. D. Matveeva
Brief Communications
  • 16 Downloads

Summary

When configurations are named with respect to the actually largest substituents, the preferred conformation for the compound (I) in the liquid phase is trans-1e3a, and for compound (II) in the liquid phase cis-1e3e with equatorial hydrogen-bonded hydroxyls; when this nomenclature, based on the actually largest substituents is used, the Auwers-Sktta rule is not reversed for the compounds (I) and (II) in the liquid state.

Keywords

Hydroxyl Liquid Phase Liquid State Prefer Conformation Large Substituent 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. [1]
    A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 748 (1959).Google Scholar
  2. [2]
    M. I. Batuev, J. Phys. Chem. 23, 1399 (1949); 24, 381 (1950); 21, 137 (1947); 25, 884 (1951); Bull. Acad. Sci. USSR, Physics Series II, 336 (1947); 14, 429 (1950).Google Scholar
  3. [3]
    M. I. Batuev, A. A. Akhrem, A. D. Matveeva, and I. N. Nazarov, Proc. Acad. Sci. USSR, 117, 423 (1957); Bull. Acad. Sci. USSR, Div. Chem. Sci. 1389 (1958); M. I. Batuev, A. A. Akhrem, A. D. Matveeva, A. V. Kamernitskii, and I. N. Nazarov, Proc. Acad. Sci. USSR, 120,779 (19585; Bull. Acad. Sci. USSR, Div. Chem. Sci. 556 (1959). M. I. Batuev, A. A. Akhrem, and A. D. Matveeva, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1665 (1959).Google Scholar

Copyright information

© Consultants Bureau 1960

Authors and Affiliations

  • M. I. Batuev
    • 1
    • 2
  • A. A. Akhrem
    • 1
    • 2
  • A. V. Kamernitskii
    • 1
    • 2
  • A. D. Matveeva
    • 1
    • 2
  1. 1.Institute of Mineral FuelsUSSR
  2. 2.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

Personalised recommendations