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Raman spectrum investigation of the conformations of cis and trans methyl 1- hydroxy-3- methylcyclohexane-carboxylates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

The investigated cis and trans methyl 1-hydroxy-3-methylcyclohexanecarboxylates are mixtures of conversion isomers 1e3e⇌1a3a and 1e3a⇌1a3e with predominance in the first of the conformation 1e3e and in the second of 1e3a; moreover, in each of the two mixtures there is some admixture of the other. The Auwers-Skita is reversed for the compounds obtained.

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Literature cited

  1. A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1958).

  2. F. D. Rossini and K. S. Pitzer, Science 105, 647 (1947).

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  3. M. I. Batuev, A. A. Akhrem, A. D. Matveeva, and I. N. Nazarov, Proc. Acad. Sci. USSR 117, 423 (1957); Bull. Acad. Sci. USSR, Div. Chem. Sci. (1958), 1389; M. I. Batuev, A. A. Akhrem, A. D. Matveeva, A. V. Kamernitskii, and I. N. Nazarov, Proc. Acad. Sci. USSR 120, 779 (1958).

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Authors and Affiliations

  1. Institute of Mineral Fuels of the Academy of Sciences of the USSR, USSR

    M. I. Batuev, A. A. Akhrem, A. V. Kamernitskii & A. D. Matveeva

  2. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. I. Batuev, A. A. Akhrem, A. V. Kamernitskii & A. D. Matveeva

Authors
  1. M. I. Batuev
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  2. A. A. Akhrem
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  3. A. V. Kamernitskii
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  4. A. D. Matveeva
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Batuev, M.I., Akhrem, A.A., Kamernitskii, A.V. et al. Raman spectrum investigation of the conformations of cis and trans methyl 1- hydroxy-3- methylcyclohexane-carboxylates. Russ Chem Bull 8, 530–533 (1959). https://doi.org/10.1007/BF00917717

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  • DOI: https://doi.org/10.1007/BF00917717

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