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Action of triethylaluminum and DIIS obutylaluminum hydride on some allyl compounds

  • L. I. Zakharkin
  • L. A. Savina
Article

Summary

  1. 1.

    In the reactions of triethylaluminum with CH2=CH-CH2X, in which X=OR, NR2, and SR, cleavage of the allyl C-X bond occurs with formation of the saturated hydrocarbon and (C2H5)2AlX.

     
  2. 2.

    Diisobutylaluminum hydride adds to CH2=CH-CH2X with formation of (i-C4H9)2AlCH2CH2CH2X, in which X=OR, NR2, and SR.

     
  3. 3.

    The action of diisobutylaluminum hydride on butyl vinyl ether results in the elimination of ethylene and the formation of butoxydiisobutylaluminum.

     

Keywords

Ether Hydrocarbon Vinyl Hydride Butyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau Enterprises, Inc. 1960

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • L. A. Savina
    • 1
  1. 1.Institute of Heteroorganic Compounds of the Academy of Sciences of the USSRUSSR

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