Action of triethylaluminum and DIIS obutylaluminum hydride on some allyl compounds

  • L. I. Zakharkin
  • L. A. Savina


  1. 1.

    In the reactions of triethylaluminum with CH2=CH-CH2X, in which X=OR, NR2, and SR, cleavage of the allyl C-X bond occurs with formation of the saturated hydrocarbon and (C2H5)2AlX.

  2. 2.

    Diisobutylaluminum hydride adds to CH2=CH-CH2X with formation of (i-C4H9)2AlCH2CH2CH2X, in which X=OR, NR2, and SR.

  3. 3.

    The action of diisobutylaluminum hydride on butyl vinyl ether results in the elimination of ethylene and the formation of butoxydiisobutylaluminum.



Ether Hydrocarbon Vinyl Hydride Butyl 
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Copyright information

© Consultants Bureau Enterprises, Inc. 1960

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • L. A. Savina
    • 1
  1. 1.Institute of Heteroorganic Compounds of the Academy of Sciences of the USSRUSSR

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