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Summary

  1. 1.

    The polymerization of hexafluoro-1,3-butadiene was investigated under pressure in presence of various initiators.

  2. 2.

    It was shown that diethyl peroxydicarbonate is the most effective initiator for the polymerization of hexafluoro-1,3-butadiene.

  3. 3.

    The relation of the rate of polymerization to the nature of the initiator, the temperature, and the pressure was determined.

  4. 4.

    The thermomechanical properties of the resulting polymers were determined.

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Literature cited

  1. W. T. Miller, Industr. and Engng. Chem. 39, 401 (1947).

    Google Scholar 

  2. W. T. Miller, Preparation, Properties, and Technology of Fluorine and Organic Fluorine Compounds (1951), 595.

  3. R. N. Haszeldine, J. Chem. Soc. (1952), 4423.

  4. R. N. Haszeldine, J. Chem. Soc. (1954), 4026; ibid. (1955), 3880.

  5. W. Prober and W. T. Miller, J. Am. Chem. Soc. 71, 598 (1949).

    Google Scholar 

  6. W. T. Miller, U. S. Patent 2,567,956; Chem. Abstrs. 26, 1808 (1952).

    Google Scholar 

  7. H. J. Passino, U. S. Patent 2,600,802; Chem. Abstrs. 46, 11774 (1952).

    Google Scholar 

  8. D. S. Ballantine et al., U. S. Atomic Energy Comm. BNL-294 (T-50) (1954), 18; Chem. Abstrs. 49, 1443 (1955).

    Google Scholar 

  9. B. L. Tsetlin, V. I. Gavrilov, N. A. Velikovskaya, and V. V. Kochkin, Works Lab. 22, 3, 352 (1956).

    Google Scholar 

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Korshak, V.V., Polyakova, A.M. & Suchkova, M.D. Polymerization of hexafluoro-1,3-butadiene. Russ Chem Bull 8, 1072–1076 (1959). https://doi.org/10.1007/BF00916679

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  • DOI: https://doi.org/10.1007/BF00916679

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