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Some thiolformic esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A method was developed for the preparation of the previously unknown thiolformic esters.

  2. 2.

    Benzyl, ethyl, and butyl thiolformates are described.

  3. 3.

    By reaction of benzyl thiolformate with α-toluenethiol in presence of hydrogen chloride, a quantitative yield of tribenzyl trithiolorthoformate was obtained.

  4. 4.

    Thiolformic esters can act as N-formylating agents: by the action of benzyl thiolformate on 2-aminopyridine, N-2-pyridylformamide was obtained, and in the reactions of all the thiolformic esters that we have described with phenylhydrazine, formic 2-phenylhydrazide was obtained.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    Ya. L. Gol'dfarb & E. N. Karaulova

Authors
  1. Ya. L. Gol'dfarb
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  2. E. N. Karaulova
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Gol'dfarb, Y.L., Karaulova, E.N. Some thiolformic esters. Russ Chem Bull 8, 1063–1066 (1959). https://doi.org/10.1007/BF00916677

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  • DOI: https://doi.org/10.1007/BF00916677

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