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Catalytic transformations of 1-pentene and 3-meth yl-1-butene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    At 350° and 40 atm, in contact with zinc chloride on an alumina carrier, the carbon chain of 1-pentene undergoes isomerization with formation of 31% of isopentenes, among which 2-methyl-2-butene predominates.

  2. 2.

    Under the same conditions 3-methyl-1-butene is isomerized into 2-rnethyl-1-butene and 2-methyl-2-butene, with predominance of the latter.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    N. I. Shuikin & N. A. Pozdnyak

Authors
  1. N. I. Shuikin
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  2. N. A. Pozdnyak
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Shuikin, N.I., Pozdnyak, N.A. Catalytic transformations of 1-pentene and 3-meth yl-1-butene. Russ Chem Bull 8, 1049–1052 (1959). https://doi.org/10.1007/BF00916674

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  • DOI: https://doi.org/10.1007/BF00916674

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