Summary
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1.
The hydrazine salts of sebacic and phthalic acids were prepared and their properties were investigated.
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2.
The polycondensation of sebacic acid with hydrazine at a molar ratio of 1:1 leads to the formation of a polyhydrazide.
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3.
The polycondensation of dicarboxylic acids with hydrazine at a molar ratio of one of the acid to two and more of the hydrazine under pressure leads to the formation of a “polyaminotriazote.”
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4.
A mechanism was proposed for the formation of polymers containing 4-amino-4-H-1,2,4-triazole units.
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Literature cited
V. V. Korshak, G. N. Chelnokova and M. A. Shkolina, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1959, 925.
V. W. Fisher, J. Appl. Chem. 4, 212 (1954).
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Korshak, V.V., Chelnokova, G.N. & Shkolina, M.A. Mechanism of the formation of “poly aminotria zoles”. Russ Chem Bull 8, 894–897 (1959). https://doi.org/10.1007/BF00915924
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DOI: https://doi.org/10.1007/BF00915924