Oxidation of 2-methyl-1-(1′-acetoxyethylidene)-cyclohexane with osmium tetroxide and peracetic acid

  • A. A. Akhrem
Brief Communications


The stereochemistry of oxidation of trans-2-methyl-1-(1′-acetoxyethylidene)-cyclohexane (II) with osmic anhydride was studied and the configuration of the triol (IV) formed thereby, and of the related compounds, was determined.


Oxidation Anhydride Cyclohexane Osmium Related Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. [1]
    I. N. Nazarov and A. A. Akhrem, J. Gen. Chem. 28, 1791 (1958).Google Scholar
  2. [2]
    R. Criegee, Liebigs Ann. Chem. 522, 75 (1936).Google Scholar
  3. [3]
    K. Dimroth, Ber. 71, 1333 (1938).Google Scholar
  4. [4]
    A. Serini et al, Ber 72, 391 (1939); L. Fieser and M. Fieser, Chemistry of Natural Compounds of the Phenanthrene Series, State Chem. Press, Moscow, 1953, p. 401.Google Scholar
  5. [5]
    S. Mizushima, Structure of Molecules and Internal Rotation, Foreign Press, Moscow, 1957.Google Scholar
  6. [6]
    D. Barton and R. Cooxon, Quarterly Rev. 10, 44 (1956).Google Scholar
  7. [7]
    I. Hogg et al., J. Amer. Chem. Soc. 78, 6213 (1956).Google Scholar
  8. [8]
    I. Billimoria, J. Chem. Soc. 1953, 2626.Google Scholar

Copyright information

© Consultants Bureau Enterprises Inc 1960

Authors and Affiliations

  • A. A. Akhrem
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of SciencesUSSR

Personalised recommendations