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Effect of the medium on the stereochemistry of nucleophilic additions at the carbonyl group

  • A. V. Kamernitskii
  • A. A. Akhrem
Brief Communications
  • 16 Downloads

Summary

  1. 1.

    The dependence of the stereochemistry of the cyanohydrin synthesis on the reaction medium was investigated.

     
  2. 2.

    The stereospecificity of the reaction is somewhat lowered in a nonionic medium.

     

Keywords

Carbonyl Carbonyl Group Reaction Medium Nucleophilic Addition Nonionic Medium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. [1]
    I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1958, 631.Google Scholar
  2. [2]
    I. N. Nazarov, A. V. Kamernitskii and A. A. Akhrem, J. Gen. Chem. 28, 1458 (1958).Google Scholar
  3. [3]
    I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, J. Gen. Chem. 25, 1345 (1955).Google Scholar
  4. [4]
    J. D. Billimoria, J. Chem. Soc. 1953, 2626.Google Scholar

Copyright information

© Consultants Bureau Enterprises Inc 1960

Authors and Affiliations

  • A. V. Kamernitskii
    • 1
  • A. A. Akhrem
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of SciencesUSSR

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