Conclusions
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1.
The reaction of diphenylstibine with ethynylbenzene leads to diphenylstyrylstibine.
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2.
With carbon tetrachloride diphenylstibine forms chloroform, benzene, chlorodiphenylstibine, and hydrogen chloride, and with benzotrichloride - benzylidene chloride and chlorodiphenylstibine. A reaction scheme is proposed for this process.
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3.
The reactions of diphenylstibine with dilute hydrochloric acid, with acetic acid, and with benzoic acid go with liberation of hydrogen and lead, respectively, to chloro-, acetoxy-, and (benzoyloxy)-diphenylstibines.
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Literature cited
A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Izv. AN SSSR, Otd. khim. n.,1963, 194.
A. E. Borisov, N. V. Novikova, and N. A. Chumaevskii, Dokl. AN SSSR,136, 129 (1961).
G. J. M. Kerk, J. G. Noltes, and J. G. A. Luijten, J. Appl. Chem.,7, 356 (1957).
G. J. M. Kerk and J. G. Noltes, J. Appl. Chem.,9, 106 (1959).
M. C. Henry and J. G. Noltes, J. Amer. Chem. Soc.,82, 558 (1960).
V. F. Mironov, N. G. Dzhurinskaya, and A. D. Petrov, Dokl. AN SSSR,128, 302 (1959);131, 98 (1960).
A. E. Borisov and A. N. Abramova, Izv. AN SSSR, Ser. khim.,1964, 844.
F. Klages and W. Rapp, Ber.,88, 384 (1955).
N. N. Vorozhtsov, Khim. prom.,1947, No. 6, 23; I. N. Chawdhury and M. A. Sabur, J. Indian Chem.,14, 633 (1937).
A. E. Borisov, A. N. Abramova, and Z. N. Parnes, Izv. AN SSSR, Ser. khim.,1964, 942.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 815–818, April, 1967.
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Nesmeyanov, A.N., Borisov, A.E. & Novikova, N.V. Reactivity of diphenylstibine. Russ Chem Bull 16, 783–786 (1967). https://doi.org/10.1007/BF00915655
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DOI: https://doi.org/10.1007/BF00915655