Reactivity of diphenylstibine

  • A. N. Nesmeyanov
  • A. E. Borisov
  • N. V. Novikova
Organic and Biological Chemistry

Conclusions

  1. 1.

    The reaction of diphenylstibine with ethynylbenzene leads to diphenylstyrylstibine.

     
  2. 2.

    With carbon tetrachloride diphenylstibine forms chloroform, benzene, chlorodiphenylstibine, and hydrogen chloride, and with benzotrichloride - benzylidene chloride and chlorodiphenylstibine. A reaction scheme is proposed for this process.

     
  3. 3.

    The reactions of diphenylstibine with dilute hydrochloric acid, with acetic acid, and with benzoic acid go with liberation of hydrogen and lead, respectively, to chloro-, acetoxy-, and (benzoyloxy)-diphenylstibines.

     

Keywords

Hydrogen Acetic Chloride Benzene Acetic Acid 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Izv. AN SSSR, Otd. khim. n.,1963, 194.Google Scholar
  2. 2.
    A. E. Borisov, N. V. Novikova, and N. A. Chumaevskii, Dokl. AN SSSR,136, 129 (1961).Google Scholar
  3. 3.
    G. J. M. Kerk, J. G. Noltes, and J. G. A. Luijten, J. Appl. Chem.,7, 356 (1957).Google Scholar
  4. 4.
    G. J. M. Kerk and J. G. Noltes, J. Appl. Chem.,9, 106 (1959).Google Scholar
  5. 5.
    M. C. Henry and J. G. Noltes, J. Amer. Chem. Soc.,82, 558 (1960).Google Scholar
  6. 6.
    V. F. Mironov, N. G. Dzhurinskaya, and A. D. Petrov, Dokl. AN SSSR,128, 302 (1959);131, 98 (1960).Google Scholar
  7. 7.
    A. E. Borisov and A. N. Abramova, Izv. AN SSSR, Ser. khim.,1964, 844.Google Scholar
  8. 8.
    F. Klages and W. Rapp, Ber.,88, 384 (1955).Google Scholar
  9. 9.
    N. N. Vorozhtsov, Khim. prom.,1947, No. 6, 23; I. N. Chawdhury and M. A. Sabur, J. Indian Chem.,14, 633 (1937).Google Scholar
  10. 10.
    A. E. Borisov, A. N. Abramova, and Z. N. Parnes, Izv. AN SSSR, Ser. khim.,1964, 942.Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • A. E. Borisov
    • 1
  • N. V. Novikova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

Personalised recommendations