Skip to main content
SpringerLink
Log in

A case of slow hydrogen exchange in the\(\begin{array}{*{20}c} \backslash \\ / \\ \end{array} N - H\) group

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It was found that the isotopic exchange of the hydrogen of the NH group of diethyl 3,5-dimethly-2,4-pyrroledicarboxylate proceeds relatively slowly.

  2. 2.

    A study was made of the kinetics of this reaction at various temperatures.

  3. 3.

    The slow hydrogen exchange that occurs in this case is interpreted from the point of view of A. I. Brodsskii's theory.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. A. I. Brodskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1949, 3; J. Gen. Chem. 24, 413 (1954); Ukrainian Chem. J. 22,11, (1956); Proc. Acad. Sci. USSR 74, 299, 513 (1950).

  2. J. Hine and C. H. Thomas, J. Amer. Chem. Soc. 75, 739 (1953); 76, 612 (1954); H. Kwart, L. P. Kuhn, and E. L. Bannister, J. Amer. Chem. Soc. 76, 5998 (1954); A. B. Burg, J. Amer. Chem. Soc. 69, 747 (1947); C. G. Swain, J. Amer. Chem. Soc. 76, 4243 (1954).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    D. N. Kursanov, Z. N. Parnes & R. G. Kononova

Authors
  1. D. N. Kursanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. N. Parnes
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. G. Kononova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kursanov, D.N., Parnes, Z.N. & Kononova, R.G. A case of slow hydrogen exchange in the\(\begin{array}{*{20}c} \backslash \\ / \\ \end{array} N - H\) group. Russ Chem Bull 7, 1442–1443 (1958). https://doi.org/10.1007/BF00914862

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00914862

Keywords

Search

Navigation