Skip to main content
SpringerLink
Log in

Direct synthesis of 1,1-dichlorosilylcyclopentane

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The behavior of 1,4-dichlorobutane in direct synthesis was investigated. It was shown that the main reaction product is 1,1-dichlorosilacyclopentane.

  2. 2.

    The reaction of 1,1-dichlorosilacyclopentane with sulfuryl chloride, acetic anhydride, allylmagnesium bromide, and aqueous alkali were studied.

  3. 3.

    1,1,3-Trichlorosilacyclopentane, which is formed in the chlorination of 1,1-dichlorosilacyclopentane, undergoesΒ-decomposition with opening of the ring when it reacts with a Grignard reagent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. F. Plate, N. A. Momma, and Iu. P. Egorov, Proc. Acad. Sci. USSR 97, 847 (1954).

    Google Scholar 

  2. R. West, J. Amer. Chem. Soc. 76, 6012 (1954).

    Google Scholar 

  3. R. West and E. Rochow, Naturwissenschaften 40, 142 (1953).

    Google Scholar 

  4. L. H. Sommer and C. Baut, J. Amer. Chem. Soc. 76, 5002 (1954).

    Google Scholar 

  5. A. D. Petrov, G. I. Nikishin, N. P. Smetankina and Iu. P. Egorov, Bull. Acad. Sci. USSR; Div. Chem. Sci. 947 (1955).

  6. W. D. English, A. Taurins and R. V. Nicholls, Canad. J. Chem. 30, 646 (1952).

    Google Scholar 

  7. L. H. Sommer, G. M. Goldberg, E. Dorfman and F. C. Whitmore, J. Amer. Chem. Soc. 68, 1083 (1946).

    Google Scholar 

  8. A. D. Petrov and G. I. Nikishin, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1952, 1128.

  9. P. D. George, L. H. Sommer, F. C. Whitmore, J. Amer. Chem. Soc. 75, 1585 (1953).

    Google Scholar 

  10. A. I. Uvala, Bericht. 63, 1992 (1930).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    A. D. Petrov, N. P. Smetankina & G. I. Nikishin

Authors
  1. A. D. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. P. Smetankina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. I. Nikishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrov, A.D., Smetankina, N.P. & Nikishin, G.I. Direct synthesis of 1,1-dichlorosilylcyclopentane. Russ Chem Bull 7, 1414–1417 (1958). https://doi.org/10.1007/BF00914854

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00914854

Keywords

Search

Navigation