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Benzoic acylals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Summary

  1. 1.

    A method was developed for the synthesis of 1-alkylethyl benzoates (acylals) in yields of 80–90% and higher.

  2. 2.

    The following compounds were synthesized for the first time by this method: CH3CH(OR)OCOC6H5, in which R=(CH3)2CH, C4H9, C6H13, C6H11, C6H5, p-CH3C6H4, o-CH3C6H4.

  3. 3.

    Compounds of this type in which R is an alkyl group are unstable to keeping and are extremely sensitive to acid reagents and to heat.

  4. 4.

    Phosphoric oxide is an extremely active catalyst for the polymerization of alkyl vinyl ethers.

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Literature cited

  1. W. E. Kass, J. Amer. Chem. Soc. 69, 500 (1947).

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  2. M. F. Shostakovskii, N. A. Gershtein, and V. A. Neterman, Doklady Akad. Nauk SSSR 103. 2, 265 (1955).

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  3. N. A. Gershtein and M. F. Shostakovskii, Zhur. Obshchei Khim. 18, 1689 (1948).

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  4. Beilstein, 9, 114 (1926).

  5. Beilstein, 9, 113 (1926).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovskii, N. A. Gershtein & V. A. Neterman

Authors
  1. M. F. Shostakovskii
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  2. N. A. Gershtein
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  3. V. A. Neterman
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Shostakovskii, M.F., Gershtein, N.A. & Neterman, V.A. Benzoic acylals. Russ Chem Bull 8, 1916–1920 (1959). https://doi.org/10.1007/BF00914767

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  • DOI: https://doi.org/10.1007/BF00914767

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