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Influence of solvents on the radical decomposition of ketohydroperoxide

  • G. E. Zaikov
  • Z. K. Maizus
  • N. M. Émanuél'
Physical Chemistry
  • 26 Downloads

Conclusions

  1. 1.

    In the oxidation of methyl ethyl ketone, two hydroperoxides are formed: anα-ketohydroperoxide and a hydroperoxide of unknown structure.

     
  2. 2.

    Each of the hydroperoxides can be added to methyl ethyl ketone, forming hydroperoxides of the type R'C(OH)(RO2)R. The rate of decomposition of these hydroperoxides into radicals is lower than that of the free hydroperoxides.

     
  3. 3.

    When methyl ethyl ketone is diluted with benzene, the equilibrium concentration of such stable hydroperoxides is reduced, which leads to an increase in the rate of formation of radicals in the system.

     

Keywords

Oxidation Methyl Ethyl Benzene Ketone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • G. E. Zaikov
    • 1
  • Z. K. Maizus
    • 1
  • N. M. Émanuél'
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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