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Über die Entstehung von Oligoanthrylen bei der milden Sulfonierung von Anthracen

The formation of oligo-anthrylenes on mild sulfonation of anthracene

  • Organische Chemie und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The sulfonation of anthracene yields a variety of products and byproducts by different reaction paths depending on the reaction conditions. While trying to reduce the number of products formed by sulfonation under mild conditions, a new reaction was found: under certain sulfonation conditions anthracene is not sulfonated but reacts to form oligoanthrylenes. The highest average molecular weight of a fraction, insoluble in benzene, is about 3,000.

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Literatur

  1. E. Clar, Polycyclic Hydrocarbons. London-New York: Academic Press. 1964.

    Google Scholar 

  2. P. H. Gore, J. org. Chem.22, 135 (1957).

    Google Scholar 

  3. C. M. Suter undA. W. Weston, Organic Reactions; 5. Aufl., Vol. III, S. 141. New York: Wiley. 1949.

    Google Scholar 

  4. P. Friedlaender, Fortschritte der Teerfarbenfabrikation11, 537 (1912 bis 1914). Berlin: Springer.

    Google Scholar 

  5. M. Battegay undP. Brandt, Bull. Soc. chim. France31, 910 (1922).

    Google Scholar 

  6. H. Zorn, O. Hinterhofer undH. Schindlbauer, Mh. Chem.98, 2406 (1967).

    Google Scholar 

  7. K. Nakanishi, Infrared Absorption Spectroscopy-Practical. San Francisco: Holden Day. 1962.

    Google Scholar 

  8. F. Bell undD. M. Waring, J chem. Soc. [London]1949, 2689.

  9. W. Minajew undB. Fedorow, Ber. dtsch. chem. Ges.62, 2489 (1929).

    Google Scholar 

  10. E. de Barry Barnett, Ber. dtsch. chem. Ges.65, 518 (1932).

    Google Scholar 

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Authors and Affiliations

  1. Forschungs- und Entwicklungszentrum der Firma Wilhelm Anger GmbH, Benatzkygasse 2-6, A-1220, Wien, Österreich

    Otto Hinterhofer

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  1. Otto Hinterhofer
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Hinterhofer, O. Über die Entstehung von Oligoanthrylen bei der milden Sulfonierung von Anthracen. Monatshefte für Chemie 106, 67–72 (1975). https://doi.org/10.1007/BF00914500

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  • DOI: https://doi.org/10.1007/BF00914500

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