Conclusions
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1.
Lithium-o-carboranes (by the example of 1-methyl-2-lithium-o-carborane) react with perfluorolefins (tetrafluoroethylene, trifluorochloroethylene, and perfluoroisobutylene) with replacement of one or two fluorine atoms by the carbonyl group to form fluoroalkylenyl-o-carboranes.
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2.
The authors have studied the chemical shifts and reaction constants in these fluoroalkenylcarboranes.
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Literature cited
P. Tarrant and D. Warnes, J. Amer. Chem. Soc.,76, 1624 (1954).
S. Dixon, J. Organ. Chem.,21, 400 (1956).
I. L. Knuyants, P. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Otd. Khim. N., 221 (1960).
B. L. Dyatkin, Yu. S. Konstantinov, L. T. Lantseva, R. A. Bekker, and I. L. Khunyants, Zh. Org. Khim.,6, 1006 (1957).
C. A. Reilly and J. D. Swalen, J. Amer. Chem. Phys.,34, 2122 (1963).
S. Andreades, J. Amer. Chem. Soc.,84, 864 (1962).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 190–192, January, 1970.
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Zakharkin, L.I., Lebedev, V.N. Synthesis of fluoroalkenyl-o-carboranes. Russ Chem Bull 19, 194–196 (1970). https://doi.org/10.1007/BF00913961
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DOI: https://doi.org/10.1007/BF00913961