Conclusions
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1.
The reaction of iminoxyl radicals with chlorine at a low temperature has led to the formation of diamagnetic oxidation products of the radicals.
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2.
According to the IR and UV spectroscopic data the obtained compounds are 1-oxopiperidinium chlorides.
Literature cited
V. A. Golubev, É. G. Rozantsev, and M. B. Neiman, Izv. Akad. Nauk SSSR, Ser. Khim., 1927 (1965).
J. W. Linnet and R. M. Rosenberg, Tetrahedron,20, 53 (1964).
O. L. Lebedev and S. N. Kazarnovskii, Transactions on Chemistry and Chemical Technology [in Russian], No. 3, Gor'kii (1959), p. 649.
É. G. Rozantsev and V. A. Golubev, Izv. Akad. Nauk SSSR, Ser. Khim., 391 (1965).
M. B. Neiman, E. G. Rozantsev, and Yu. G. Mamedova, Nature,196, 472 (1962).
É. G. Rozantsev and V. A. Golubev, Izv. Akad. Nauk SSSR, Ser. Khim., 718 (1965).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp. 184–185, January, 1970.
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Golubev, V.A., Zhdanov, R.I. & Rozantsev, É.G. Reaction of iminoxyl radicals with chlorine. Russ Chem Bull 19, 186–187 (1970). https://doi.org/10.1007/BF00913958
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DOI: https://doi.org/10.1007/BF00913958