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Radiochemical telomerization of ethylene with methyl formate

  • I. N. Bryantsev
  • P. A. Zagorets
  • N. N. Romina
  • A. B. Terent'ev
  • R. Kh. Freidlina
Brief Communications

Conclusions

  1. 1.

    The radiochemical telomerization of ethylene with methyl formate has been studied over the temperature range 125–190°.

     
  2. 2.

    A rearrangement of radicals with 1,6-migration of hydrogen atoms took place during the course of the reaction.

     

Keywords

Hydrogen Methyl Ethylene Hydrogen Atom Methyl Formate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    R. Kh. Freidlina, E. I. Vasil'eva, E. Ts. Chukovskaya, and B. A. Énglin, in: Progress in the Chemistry of Polymers [in Russian], Khimiya (1966), p. 156.Google Scholar
  2. 2.
    C. F. Stoops, USA Patent No. 3105802; Ref. Zh. Khim., 10N47P (1965).Google Scholar
  3. 3.
    A. B. Terent'ev and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1854 (1966).Google Scholar
  4. 4.
    W. H. Urry and E. S. Huyser, J. Am. Chem. Soc.,75, 4876 (1953).Google Scholar
  5. 5.
    G. N. Nikishin, V. D. Vorob'ev and A. D. Petrov, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, 1488 (1957).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • I. N. Bryantsev
    • 1
    • 2
  • P. A. Zagorets
    • 1
    • 2
  • N. N. Romina
    • 1
    • 2
  • A. B. Terent'ev
    • 1
    • 2
  • R. Kh. Freidlina
    • 1
    • 2
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR
  2. 2.D. I. Mendeleev Moscow Chemicotechnological InstituteUSSR

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