Conclusions
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1.
The oxidative dehydrogenation of n-hexane and cyclohexane in the presence of hydrochloric acid and aniron — silicagel catalyst at 550–580° has been studied. The formation of the corresponding unsaturated hydrocarbons and benzene is the main reaction course.
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2.
Cyclohexane and methylcyclopentane are more stable to the oxidative dehydrogenation reaction under the conditions studied than n-hexane.
Literature cited
G. A. Tarasova and Z. A. Solomatina, Izv. Akad. Nauk SSSR, Ser. Khim., 1288 (1969).
A. P. Reznik, I. Ya. Tyuryaev, and V. P. Musienko, Khim. Prom. Ukrainy, Nauchnoproizvod. Sb. No. 4 (34), 14 (1967).
USA Patent 3308185-3308198; Official Gazette,836, section II, Chemistry No. 1 (10), p. 72
USA Patent 2661380; Chem. Abstrs.,48, 6683 (1954); French Patent 1385650; Chem. Abstrs.,62, 13043 (1965); French Patent 1407830; RZhKhim., 12N20 (1967).
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Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 166–168, January, 1970.
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Tarasova, G.A., Rozengart, M.I., Dubinskii, Y.G. et al. Oxidative dehydrogenation of alkanes and cycloalkanes. Russ Chem Bull 19, 162–164 (1970). https://doi.org/10.1007/BF00913949
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DOI: https://doi.org/10.1007/BF00913949