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Oxidative dehydrogenation of alkanes and cycloalkanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The oxidative dehydrogenation of n-hexane and cyclohexane in the presence of hydrochloric acid and aniron — silicagel catalyst at 550–580° has been studied. The formation of the corresponding unsaturated hydrocarbons and benzene is the main reaction course.

  2. 2.

    Cyclohexane and methylcyclopentane are more stable to the oxidative dehydrogenation reaction under the conditions studied than n-hexane.

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Literature cited

  1. G. A. Tarasova and Z. A. Solomatina, Izv. Akad. Nauk SSSR, Ser. Khim., 1288 (1969).

  2. A. P. Reznik, I. Ya. Tyuryaev, and V. P. Musienko, Khim. Prom. Ukrainy, Nauchnoproizvod. Sb. No. 4 (34), 14 (1967).

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Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 166–168, January, 1970.

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Tarasova, G.A., Rozengart, M.I., Dubinskii, Y.G. et al. Oxidative dehydrogenation of alkanes and cycloalkanes. Russ Chem Bull 19, 162–164 (1970). https://doi.org/10.1007/BF00913949

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  • DOI: https://doi.org/10.1007/BF00913949

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