Conclusions
The frequencies of the =CH2 group wagging vibration in CH2=CH-X compounds reflects both the inductive effect of the substituents X, and the effects ofπ, π-, π,p- and (d-p)π-conjugation in which these substituents take part.
Literature cited
A. N. Egorochkin, A. I. Burov, V. F. Mironov, T. K. Gar, and N. S. Vyazankin, Izv. Akad. Nauk SSSR, Ser. Khim., 775 (1969).
G. A. Razuvaev, A. N. Egorochkin, S. Ya. Khorshev, N. S. Vyazankin, and V. F. Mironov, Dokl. Akad. Nauk SSSR,185, 100 (1969).
L. A. Leites, I. D. Pavlova, and Yu. P. Egorov, Teoret. i Éksperim. Khimiya,1, 311 (1965).
W. J. Potts and R. A. Nyquist, Spectrochim. Acta,15, 679 (1959).
A. N. Egorochkin, S. Ya. Khorshev, N. S. Vyazankin, and E. N. Gladyshev, Izv. Akad. Nauk SSSR, Ser. Khim., 1868 (1969).
J. J. Eisch and J. T. Trainer, J. Organ. Chem.,28, 487 (1963).
S. S. Batsanov, Uspekhi Khimii,37, 778 (1968).
Yu. P. Egorov and G. G. Kirei, Zh. Obshch. Khimii,34, 3615 (1964).
V. A. Pal'm, Uspekhi Khimii,30, 1069 (1961).
J. Knizek, M. Horak, and V. Chvalovsky, Coll. Czechosl. Chem. Comm.,28, 3079 (1963).
R. H. Fish, H. G. Kuivila, and I. J. Tyminski, J. Amer. Chem. Soc.,89, 5861 (1967).
R. W. Taft, in: Steric Effects in Organic Chemistry [Russian translation], IL (1960), Chapter 13.
O. Éksner, Trans. of Conference on the Use of Correlation Equations in Organic Chemistry [in Russian], Vol. 1, Tartu (1962), p. 67.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.l, pp. 152–154, January 1970.
Rights and permissions
About this article
Cite this article
Egorochkin, A.N., Semchikov, Y.D., Vyazankin, N.S. et al. Infrared spectra of vinyl compounds and the effects of conjugation involving the π-electrons of the vinyl group. Russ Chem Bull 19, 143–145 (1970). https://doi.org/10.1007/BF00913942
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00913942